77532-84-4Relevant academic research and scientific papers
Copper-catalyzed cyclization of 2-cyanobenzaldehydes and 2-isocyanoacetates: An efficient strategy for the synthesis of substituted 1-aminoisoquinolines
Bao, Wen,Wang, Jun-Qi,Xu, Xue-Tao,Zhang, Bang-Hong,Liu, Wei-Ting,Lei, Lin-Sheng,Liang, Huan,Zhang, Kun,Wang, Shao-Hua
supporting information, p. 8194 - 8197 (2018/07/29)
A Cu(acac)2-catalyzed cyclization reaction of 2-cyanobenzaldehydes with 2-isocyanoacetates has been successfully developed providing an efficient strategy for the synthesis of substituted 1-aminoisoquinolines. The reaction proceeds smoothly under mild conditions with high efficiency, and might provide an alternative strategy for the synthesis of 1-aminoisoquinoline containing molecules.
CYCLIC IMIDATE LIGANDS
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Page/Page column 7, (2012/04/05)
The present invention relates to a use of a cyclic imidate as a ligand for catalysis in which the ligand contains sub-structure (Y) as a minimal structural motive, wherein the carbon atoms and the nitrogen atom can be optionally substituted by a chemical substituent.
Efficient one-step synthesis of chiral bidentate oxazoline-alcohol ligands via a cyclic imidate ester rearrangement
Noel, Timothy,Robeyns, Koen,Meervelt, Luc Van,Eycken, Erik Van der,Eycken, Johan Van der
experimental part, p. 1962 - 1968 (2010/03/03)
Various chiral bidentate oxazoline-alcohol ligands were obtained in a straightforward one-step synthesis via a cyclic imidate ester rearrangement. These chiral ligands were tested and compared in asymmetric diethylzinc additions to aldehydes resulting in
