77584-35-1Relevant academic research and scientific papers
CHLOROETHOXY(TRIMETHYL)SILANE : A HARD-BASE TRAP WHICH PRESERVES TMS ETHER GROUPS AND IMPROVES THE WITTIG METHYLENATION OF GIBBERELLINS
Mander, Lewis N.,Turner, John V.
, p. 4149 - 4152 (2007/10/02)
A reagent, 2-chloroethoxy(trimethyl)silane (CETS), has been devised which ensures the preservation of TMS ether groups during Wittig methylenation in protic media and which makes this formerly capricious reaction with 16-keto gibberellins a reliable and straightforward procedure.
TOTAL SYNTHESIS OF GIBBERELLIN A4
Cossey, Ailsa L.,Lombardo, Luciano,Mander, Lewis N.
, p. 4383 - 4386 (2007/10/02)
A general approach to the preparation of 13-deoxy C19 gibberellins has been established with the total synthesis of (+/-)gibberellin A4 (3).
