77611-20-2Relevant academic research and scientific papers
Conversion of glycals into vicinal-1,2-diazides and 1,2-(or 2,1)-azidoacetates using hypervalent iodine reagents and Me3SiN3. Application in the synthesis of: N -glycopeptides, pseudo-trisaccharides and an iminosugar
Chennaiah, Ande,Bhowmick, Srijita,Vankar, Yashwant D.
, p. 41755 - 41762 (2017)
Glycals were found to react with a reagent system comprising of phenyliodine bis(trifluoroacetate) (PIFA) and Me3SiN3 in the presence of TMSOTf as a catalyst to form the corresponding vicinal 1,2-diazides. On the other hand, they rea
Synthesis of N-Glycosides.Formation of Glucosylamine by Reaction of 2,3,4,6-Tetra-O-benzyl-D-glucopyranose with Acetonitrile in the Presence of Trifluoromethanesulfonic Anhydride
Pavia, Andre A.,Ung-Chhun, Sak N.,Durand, Jean-L.
, p. 3158 - 3160 (2007/10/02)
The synthesis of glucosylamine by reaction of 2,3,4,6-tetra-O-benzyl-D-glucopyranose with acetonitrile in the presence of trifluoromethanesulfonic anhydride was shown to proceed through an intermediate oxazoline.
