77645-50-2Relevant academic research and scientific papers
PIFA-Mediated Dearomatizative Spirocyclization of Phenolic Biarylic Ketones via Oxidation and C-C Bond Cleavage
Zhao, Gui-Hua,Li, Bi-Qing,Wang, Shuang-Shuang,Liu, Man,Chen, Yuan,Wang, Bin
, p. 9367 - 9374 (2020)
The dearomatizing spirocyclization of phenolic biarylic ketones using PhI(OCOCF3)2 as oxidant is presented. The reaction affords various cyclohexadienones through C-C bond cleavage under mild conditions. Mechanistic investigations reveal that an exocyclic
