77670-23-6

Upstream product

• 4694-17-1 5,5-dimethlycyclohex-2-en-1-one 
• 108-98-5 thiophenol 
• 96530-09-5 5,5-dimethyl-3-phenylthio-2-cyclohexenol 
• 13271-49-3 3-bromo-5,5-dimethlycyclohex-2-en-1-one 
• 72035-56-4 5,5-dimethyl-3-phenoxycyclohex-2-en-1-one 
• 96530-07-3 5,5-dimethyl-3-phenoxy-2-cyclohexenol 

Relevant academic research and scientific papers

A kinetic study of the conjugate addition of benzenethiol to cyclic enones catalyzed by a nonsymmetrical uranyl-salophen complex

(Chemical Equation Presented) The Et3N-assisted addition of benzenethiol to enones in chloroform is catalyzed with high turnover efficiency by the phenyl-substituted uranyl-salophen compound 3. Catalytic data show a close adherence to a quaterm

Catalysis of the addition of benzenethiol to 2-cyclohexen-1-ones by uranyl-salophen complexes: A catalytic metallocleft with high substrate specificity

The base induced addition of benzenethiol to 2-cyclohexen-1-one and its 4,4-, 5,5- and 6,6-dimethyl derivatives is catalysed by a salophen-uranyl based metallocleft 2 in chloroform solution with high turnover efficiency and low product inhibition. Analysi

Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. I. Reduction of β-Phenylthio-α,β-unsaturated Cyclic Ketones

5,5,Dimethyl-3-phenoxy-2-cyclohexenone (Ib) was reduced with lithium aluminum hydride (LAH) to give the 1,2-addition product (IIIa). 2-Methyl-3-phenoxy-2-cyclopentetnone (IIa) gave a mixture of the allyl alcohol (IVa) and 1,2-addition product (IVb).On the

Asymmetric Induction in the Michael Reaction by Means of Chiral Phase-transfer Catalysts derived from Cinchona and Ephedra Alkaloids

Asymmetric induction in the Michael reaction has been achieved using alkaloidonium salts in a two-phase system with optical yields of up to 36 and 26percent in the addition to αβ-unsaturated ketones of thiols and nitroalkanes respectively.The presence of a hydroxy-group β to the 'onium function is essential to achieve substantial asymmetric syntheses.