77704-36-0Relevant academic research and scientific papers
Rearrangement of 2-Bromo-3-hydroxysantanolides Using Silver Carbonate on Celite
Jorapur, V. S.,Shaligram, A. M.
, p. 906 - 908 (2007/10/02)
Silver carbonate-on-celite rearrangements of 2-bromo-3-hydroxysantanolides (3-5) are described. cis-Bromohydrin (3) furnishes the aldehyde (6) and α-tetrahydrosantonin (2) while trans-diequatorial bromohydrin (4) and trans-diaxial bromohydrin (5) afford aldehyde (6) and α-oxide (9) respectively as the only products.
