77767-35-2

Basic information

• Product Name: 2,2-diphenyl-3-(dimethylamino)-2H-azirine
• Synonyms: 2,2-diphenyl-3-(dimethylamino)-2H-azirine
• CAS NO: 77767-35-2
• Molecular Weight: 236.316
• Mol File: 77767-35-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2-diphenyl-3-(dimethylamino)-2H-azirine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-diphenyl-3-(dimethylamino)-2H-azirine(77767-35-2)
• EPA Substance Registry System: 2,2-diphenyl-3-(dimethylamino)-2H-azirine(77767-35-2)

Safety Data

• Hazardous Substances Data: 77767-35-2(Hazardous Substances Data)

Upstream product

• 957-51-7 diphenamid 
• 54191-80-9 N,N-dimethyl-2,2-diphenylthioacetamide 
• 117-34-0 2,2-diphenylacetic acid 
• 142761-93-1 5-(Dimethylamino)-4,4-diphenyl-4H-1,2,3-triazol 
• 116437-56-0 (1-Chloro-2,2-diphenyl-vinyl)-dimethyl-amine 

Downstream Products

• 116437-58-2 4-(dimethylamino)-5,5-diphenyl-3-imidazolin-2-one 
• 106723-34-6 2,4,4-Triphenyl-1,3-thiazol-5(4H)-thion 
• 116437-60-6 4-(dimethylamino)-5,5-diphenyl-3-imidazoline-2-thione 

Relevant articles and documents

exolendo preferences of double bonds in three-membered ring compounds - The bias toward endocyclic unsaturation in 3-alkyl- and 3-amino-2H-azirines: A theoretical and experimental study

Irradiation of the amino-4H-1,2,3-triazoles (λ ≥ 280 nm) affords molecular nitrogen and 3-amino-2H-azirines in high yields. As shown on the basis of spectroscopic evidence, the photoproduct of a exists exclusively as 3-amino-2H-azirine a rather than in an

Synthesis of 4,4-Disubstituted 1,3-Thiazol-5(4H)-thiones

An easy synthesis for the 1,3-thiazol-5(4H)-thiones 5, a class of heterocycles which have hitherto only been available with difficulty, is described.Reaction of 3-amino-2H-azirines 25 with thiocarboxylic acids at 0 deg yields monothiodiamides of type 20 (Scheme 6) which, on treatment with Lawesson reagent at 100 deg, undergo thiation and cyclization to give 5 in good yield.