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Trimethylsilylcyanid als Umpolungsreagens, VII. Nucleophile Acylierung von Carbonylverbindungen mit α,β-ungesaettigten Aldehyden
Huenig, Siegfried,Oeller, Manfred
, p. 959 - 967 (2007/10/02)
The addition products 9 - 12 of trialkylsilyl cyanide with conjugated aldehydes react as their anions 9A - 12A exclusively in the α-position with ketones and aldehydes, accompanied by a 1,4-O,O-silyl rearrangement (13, 15, 18, 19).The formation of 2:1 add
