777862-18-7

Basic information

• Product Name: cis-[Pt(C₆F₅)2(1,8-naphthyridine)]
• CAS NO: 777862-18-7
• Molecular Weight: 659.345
• Mol File: 777862-18-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-[Pt(C₆F₅)2(1,8-naphthyridine)](CAS DataBase Reference)
• NIST Chemistry Reference: cis-[Pt(C₆F₅)2(1,8-naphthyridine)](777862-18-7)
• EPA Substance Registry System: cis-[Pt(C₆F₅)2(1,8-naphthyridine)](777862-18-7)

Safety Data

• Hazardous Substances Data: 777862-18-7(Hazardous Substances Data)

Upstream product

• 254-60-4 1,8-naphthyridine 

Downstream Products

• 777862-19-8 cis-[Pt(C₆F₅)2(CO)(1,8-naphthyridine)] 
• 1066876-21-8 [Pt(C6F5)(1,8-naphthyridine)(μ-PPh2)2Pt(C6F5)(1,8-naphthyridine)] 
• 1066876-19-4 [PtCl(C6F5)(μ-1,8-naphthyridine)2PtCl(C6F5)] 
• 1066880-12-3 cis-[Pt(C₆F₅)2(HPPh₂)(1,8-naphthyridine)] 
• 1066876-22-9 [Pt₂(C₆F₅)3(C₂Ph)(1,8-naphthyridine)2] 
• 1066876-24-1 cis-[Pt(C₆F₅)2Cl(1,8-naphthyridine(+1H))]*H₂O 

Relevant articles and documents

Hydrogen-bond mediation of supramolecular aggregation in neutral bis-(C6F5)Pt complexes with aromatic H-bond donating ligands. A synthetic and structural study

Six pentafluorophenylplatinum(II) complexes containing proton acceptor atoms (F) and pyridine-like aromatic ligands able to act as proton donors have been synthesized and characterized, with emphasis on the factors that mediate their supramolecular aggregation in the solid state - hydrogen bonds and π-π interactions. The crystal structure analyses of the mononuclear complexes cis-[Pt(C6F5)2(napy)] (1), cis-[Pt(C6F5)2(CH2napy)] (3), cis-[Pt(C6F5)2(2-ammpy)] (5), and cis-[Pt(C6F5)2(2-bipym)] (6) reveal the influence of D-H...Pt and D-H...F (D = C, N) hydrogen bonding on the organization of molecules into stacks, which can be further interconnected to generate channels. The prevalence of hydrogen bonding over π-π interactions between aromatic rings in establishing the nature of the observed supramolecular aggregation is demonstrated.