777902-54-2Relevant academic research and scientific papers
Facile one-pot syntheses of bromoacetylenes from bulky trialkylsilyl acetylenes
Lee, Taeho,Kang, Hee Ryong,Kim, Shinae,Kim, Sanghee
, p. 4081 - 4085 (2007/10/03)
Because haloalkynes are versatile intermediates in synthetic chemistry, the development of new efficient methods for the conversion of 1-trialkylsilylacetylenes to haloacetylenes in situ remains desirable, especially when the corresponding terminal acetyl
A new, iterative strategy for the synthesis of unsymmetrical polyynes: Application to the total synthesis of 15,16-dihydrominquartynoic acid
Kim, Sanghee,Kim, Shinae,Lee, Taeho,Ko, Hyojin,Kim, Deukjoon
, p. 3601 - 3604 (2007/10/03)
(Chemical Equation Presented) A new iterative strategy for the synthesis of unsymmetrically substituted polyynes has been developed. The starting bromoalkyne is homologated by one acetylene unit through palladium-catalyzed cross-coupling with a TIPS-prote
