777943-02-9Relevant academic research and scientific papers
Highly stereoselective addition of silylphosphines to chiral aldehydes
Kolodiazhnyi, Oleg I.,Guliaiko, Irina V.,Kolodiazhna, Anastasia O.
, p. 6955 - 6957 (2004)
The reaction between diphenyl(trimethylsilyl)phosphine or bis(trimethylsilyl)phenylphosphine and chiral aldehydes proceeds with high stereoselectivity to give diastereomerically pure tertiary α- siloxyalkylphosphines. The reaction between diphenyl(trimeth
Diasteroselective addition of mono- and bis-silylphosphines to chiral aldehydes
Kolodiazhna, Anastasia O.,Guliaiko, Irina V.,Kolodiazhnyi, Oleg I.
, p. 2335 - 2346 (2007/10/03)
The addition of silylphosphines to chiral aldehydes proceeds with high diastereoselectivity to give optically pure tertiary α- trimethylsiloxyalkylphosphines. The diastereomeric excesses of the addition products were achieved to 90-100%. The reaction of b
