777950-90-0Relevant academic research and scientific papers
Cyclizations of silyl enol ether radical cations - The cause of the stereoselectivity
Bunte, Jens O.,Heilmann, Eike K.,Hein, Birka,Mattay, Jochen
, p. 3535 - 3550 (2004)
We have used photoinduced electron transfer (PET) activation of silyl enol ethers for the synthesis of tricyclic hydrocarbons. The mechanism of this reaction was investigated by conducting independent radical-induced cyclizations of corresponding iodo ket
Synthesis and PET oxidative cyclization of silyl enol ethers: Build-up of quasi-steroidal carbocycles
Bunte, Jens O.,Rinne, Stefanie,Sch?fer, Christian,Neumann, Beate,Stammler, Hans-Georg,Mattay, Jochen
, p. 45 - 48 (2007/10/03)
PET oxidative cyclization of silyl enol ethers carrying suitable side chains with olefinic double bonds results in the stereoselective formation of carbocycles. Two model compounds for investigating the influence of silyl enol ether ring size are synthesi
