77825-73-1

Basic information

• Product Name: erythro-5-(Phenylseleno)-6-(p-toluenesulfonyl)decane
• CAS NO: 77825-73-1
• Molecular Weight: 451.532
• Mol File: 77825-73-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: erythro-5-(Phenylseleno)-6-(p-toluenesulfonyl)decane(CAS DataBase Reference)
• NIST Chemistry Reference: erythro-5-(Phenylseleno)-6-(p-toluenesulfonyl)decane(77825-73-1)
• EPA Substance Registry System: erythro-5-(Phenylseleno)-6-(p-toluenesulfonyl)decane(77825-73-1)

Safety Data

• Hazardous Substances Data: 77825-73-1(Hazardous Substances Data)

Upstream product

• 7433-78-5 cis-5-decene 
• 68819-94-3 p-tolyl benzeneselenosulfonate 
• 7433-56-9 (E)-5-decene 

Downstream Products

• 77825-84-4 (Z)-5-(p-Toluenesulfonyl)-5-decene 
• 77825-85-5 (E)-5-(p-Toluenesulfonyl)-5-decene 

Relevant articles and documents

Selenosulfonation: Boron Trifluoride Catalyzed or Thermal Addition of Selenosulfonates to Olefins. A Novel Regio- and Stereocontrolled Synthesis of Vinyl Sulfones.

Se-Phenyl areneselenosulfonates 1 add to a variety of olefins to produce β-phenylseleno sulfones 2.The reaction may be performed in the presence of boron trifluoride etherate to produce chiefly or exclusively Markovnikov products arising from a stereospecific anti addition.Alternatively, the addition may be thermally induced to afford anti-Markovnikov products generated by a nonstereospecific free-radical process.The two modes of addition achieve complementary regiospecificity.The β-phenylseleno sulfones are converted in high yield to vinyl sulfones by stereospecific oxidation-elimination with m-chloroperbenzoic acid.