77826-31-4Relevant academic research and scientific papers
Iodobenzene-catalyzed oxidative cleavage of olefins to carbonyl compounds
Du, Lele,Wang, Zechao,Wu, Junliang
supporting information, (2020/07/20)
A metal-free approach for the oxidative cleavage of carbon–carbon double bonds of olefins to carbonyl compounds was established by using oxidant m-CPBA and non-metallic organocatalyst PhI in toluene/H2O. A broad scope of aromatic olefins was used. All the reactions proceeded smoothly at 35 °C in short reaction time to furnish the respective mono- and double carbonyl compounds selectively in moderate to good yields.
Auto de-bromine-coupling reactions of 1-aryl-7-bromocycloheptenes
Lee, Gon-Ann,Lee, Hsin-Yi,Wang, Wen-Chieh,Cherng, Chih-Hwa
, p. 2956 - 2961 (2014/04/17)
Auto de-bromine-coupling reactions of 1-aryl-7-bromocycloheptenes to a new series of [7-6-6] tricyclic system were described. A variety of substituents at the para-position of the phenyl were amenable to this transformation, including electron-donating groups and halides. The presence of electron-donating groups resulted in a more efficient reaction, with higher yields than the case of halides.
