77826-33-6

Upstream product

• 106-39-8 bromochlorobenzene 
• 502-42-1 cycloheptanone 
• 873-77-8 (4-chlorphenyl)magnesium bromide 

Downstream Products

• 120568-01-6 1-(4-chlorophenyl)cyclohept-1-ene 
• 39162-37-3 {3-[1-(4-Chloro-phenyl)-cycloheptyloxy]-propyl}-dimethyl-amine 
• 100199-27-7 trans-1-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-yl)cycloheptanol 
• 129500-95-4 trans-1-(4-chlorophenyl)-2-bromocycloheptanol 
• 129500-95-4 (1R,2R)-2-Bromo-1-(4-chloro-phenyl)-cycloheptanol 
• 129500-97-6 2-(4-chlorophenyl)-3-(1H-1,2,4-triazol-1-yl)cyclohept-1-ene 
• 129500-99-8 1-(4-chlorophenyl)-1,2-epoxycyclohept-1-ene 
• 129500-98-7 1-(4-chlorophenyl)cyclohept-2-en-1-ol 
• 129500-94-3 7-Bromo-1-(4-chloro-phenyl)-cycloheptene 
• 3277-80-3 (4-chlorophenyl)(cyclohexyl)methanone 
• 39162-45-3 {2-[1-(4-Chloro-phenyl)-cycloheptyloxy]-ethyl}-diisopropyl-amine 
• 39162-43-1 {3-[1-(4-Chloro-phenyl)-cycloheptyloxy]-propyl}-diethyl-amine 
• 47185-61-5 {3-[1-(4-Chloro-phenyl)-cycloheptyloxy]-2-methyl-propyl}-dimethyl-amine 
• 22657-24-5 {2-[1-(4-Chloro-phenyl)-cycloheptyloxy]-ethyl}-diethyl-amine 

Relevant academic research and scientific papers

Auto de-bromine-coupling reactions of 1-aryl-7-bromocycloheptenes

Auto de-bromine-coupling reactions of 1-aryl-7-bromocycloheptenes to a new series of [7-6-6] tricyclic system were described. A variety of substituents at the para-position of the phenyl were amenable to this transformation, including electron-donating groups and halides. The presence of electron-donating groups resulted in a more efficient reaction, with higher yields than the case of halides.

SYNTHESIS OF 2-AZOLYLCYCLOALKANOLS

New 2-azolylcycloalkanol derivatives (13-38) were synthesized stereoselectively by Grignard reaction of 2-azolylcyclohexanones (7,8), and particularly 2-azolylcycloheptanones (9,10) afforded one of the diastereomers of 2-azolylcycloalkanols stereospecific