77842-31-0

Basic information

• Product Name: 2-(4-methylcyclohexylidene)acetic acid
• Synonyms: 2-(4-methylcyclohexylidene)acetic acid;(4-Methylcyclohexylidene)acetic acid
• CAS NO: 77842-31-0
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.20626
• Mol File: 77842-31-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 70 °C
• Boiling Point: 90-90.5 °C(Press: 3 Torr)
• Appearance: /
• Density: 1.05179 g/cm3
• Storage Temp.: 2-8°C
• PKA: 4.25±0.41(Predicted)
• CAS DataBase Reference: 2-(4-methylcyclohexylidene)acetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methylcyclohexylidene)acetic acid(77842-31-0)
• EPA Substance Registry System: 2-(4-methylcyclohexylidene)acetic acid(77842-31-0)

Safety Data

• Hazardous Substances Data: 77842-31-0(Hazardous Substances Data)

Usage

Carboxylic acid derivative

It is a compound derived from a carboxylic acid, with a carboxyl functional group (-COOH) attached to a hydrocarbon chain.

Cyclohexylidene functional group

The molecule contains a cyclohexylidene group, which is a six-membered carbon ring with one double bond in the ring.

Synthesis of pharmaceuticals and agrochemicals

2-(4-methylcyclohexylidene)acetic acid is used as a building block or intermediate in the production of various pharmaceuticals and agrochemicals.

Reagent in organic chemistry reactions

The compound can be used as a reagent in organic chemistry reactions, such as esterification (forming esters) and amidation (forming amides).

Potential applications in fragrance and flavor industry

Due to its unique chemical structure, 2-(4-methylcyclohexylidene)acetic acid has potential uses in the fragrance and flavor industry for creating various scent and taste profiles.

Versatile compound

2-(4-methylcyclohexylidene)acetic acid is a versatile compound with diverse applications across various industries, including chemical, pharmaceutical, agrochemical, and flavor and fragrance industries.

Upstream product

• 105-36-2 ethyl bromoacetate 
• 589-92-4 1-methylcyclohexan-4-one 
• 127180-76-1 ethyl 4-methylcyclohexylideneacetate 
• 77842-31-0 (4-methylcyclohexylidene)acetic acid 
• 97777-91-8 2-(4-methylcyclohex-1-en-1-yl)acetic acid 
• 131023-61-5 cis 1-chloro-4-methylcyclohexyl acetic acid 
• 124-38-9 carbon dioxide 
• 77842-32-1 (R)-(-)-(4-Methylcyclohexylidene)bromomethane 
• 97777-88-3 (1-hydroxy-4-methyl-cyclohexyl)-acetic acid 
• 108-24-7 acetic anhydride 

Downstream Products

• 2808-80-2 4-methyl-1-methylidenecyclohexane 
• 861575-72-6 (1-bromo-4-methyl-cyclohexyl)-acetic acid 
• 119326-74-8 trans-4-methyl-1-<<(4-methylphenyl)methyl>thio>cyclohexaneacetic acid 
• 344620-51-5 1-Allylidene-4-methyl-cyclohexane 
• 344620-51-5 (aR)-(+)-(4-methylcyclohexylidene)propene 
• 131023-61-5 cis 1-chloro-4-methylcyclohexyl acetic acid 
• 131023-62-6 trans 1-chloro-4-methylcyclohexyl acetic acid 
• 56300-87-9 2-(4-Methyl-cyclohexylidene)-ethanol 
• 56300-87-9 (aR)-(-)-(4-methylcyclohexylidene)ethanol 
• 7071-18-3 (4-Methyl-cyclohexylidene)-acetaldehyde 
• 7071-18-3 (aR)-(-)-(4-methylcyclohexylidene)acetaldehyde 
• 124-38-9 carbon dioxide 
• 7071-18-3 2-(4-methylcyclohexylidene)acetaldehyde 
• 102306-26-3 (R,R)-(+)-bis(4-methylcyclohexylidene)-trans-2,3-dimethylbut-2-ene 

Relevant articles and documents

Chiral Carbenoids: Effect of TMEDA

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A Minor Modification of Residue 1 in Potent Vasopressin Antagonists Dramatically Reduces Agonist Activity

arginine-vasopressin (SK&F 101926, 1), a potent in vivo and in vitro vasopressin V2 receptor antagonist, was recently tested in human volunteers and s

ELECTRON TRANSFER FROM METAL SURFACES. FORMATION OF LITHIUM AND GRIGNARD REAGENTS.

Chiral (+)-(S)-4-methylcyclohexylidenebromomethane (1) has been prepared from (-)-(R)-4-methylcyclohexylideneacetic acid by a stereospecific bromodecarboxylation reaction.The reaction was shown to proceed with an overall inversion of configuration.The rea