778519-97-4

Basic information

• Product Name: Co((CCH₃NO)2H)2(CH₂COO)H₂O^(1-)
• Synonyms: Co((CCH₃NO)2H)2(CH₂COO)H₂O^(1-)
• CAS NO: 778519-97-4
• Molecular Weight: 365.269
• Mol File: 778519-97-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Co((CCH₃NO)2H)2(CH₂COO)H₂O^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: Co((CCH₃NO)2H)2(CH₂COO)H₂O^(1-)(778519-97-4)
• EPA Substance Registry System: Co((CCH₃NO)2H)2(CH₂COO)H₂O^(1-)(778519-97-4)

Safety Data

• Hazardous Substances Data: 778519-97-4(Hazardous Substances Data)

Upstream product

• 757895-36-6 Co((CCH₃NO)2H)2(CH₂COO)CF₃CH₂NH₂^(1-) 
• 81956-81-2 (1-carboxyethyl)(2,2-dimethoxyethylamine)bis(dimethylglyoximato)cobalt(III) 
• 81956-82-3 (1-carboxyethyl)(2-methoxyethylamine)bis(dimethylglyoximato)cobalt(III) 
• 81956-83-4 (1-carboxyethyl)(n-propylamine)cobaloxime 

Relevant articles and documents

Substituen Effect of Chelated Cobalt. 5. Acidities of (Carboxymethyl)- and (1-Carboxyethyl)cobaloximes. A Quantitative Analysis of the β Effect

pKa's of the weakly acidic (carboxymethyl)(ligand)cobaloximes and (1-carboxyethyl)(ligand)cobaloximes with 16 different axial ligands have been determined and correlated with those of 11 substituted acetic acids or 9 1-substituted propionic acids, respectively.Comparison of apparent ?1 values thus calculated with those previously determined by correlation of (carboxyethyl)(ligand)cobaloxime pKa's with the pKa's of 2-substituted propionic acid indicates that the (1-carboxyalkyl)cobalt comlexes show a substantial β effect as an apparent extreme donation density to the carboxyl carbon.The β effect in these complexes has been quantitated by use of a dual substituent parameter equation, the results of which show that the effect is only some 8-10percent enhanced in (1-carboxyethyl)cobaloximes relative to (carboxymethyl)cobaloximes.This result is consistent with the β effect being mediated by ?-? hyperconjugation rather than neighboring group participation.Structural effects on the extent of ?-? conjugation and the effects of ?-? conjugation on reactivity of the cobalt atom in these complexes are discussed.