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Barium manganate (chemical formula BaMnO4) is a type of manganate in which the manganese is in a +6 oxidation state. It is obtained by heating manganese dioxide with barium carbonate or nitrate, or by precipitating potassium manganate with barium chloride. Barium manganate gives a green pigment, which was used to make manganese blue. It can be used in the oxidation of a variety of functional groups efficiently and selectively.
Used in Art and Painting:
Barium manganate is used as a pigment in fresco painting as an alternative to Scheele's green because it is less toxic.
Used in Organic Synthesis:
Barium manganate is used as a mild oxidizing agent in organic synthesis for the selective oxidation of various functional groups, such as alcohols to carbonyls, alcohols to aldehydes, diols to lactones, thiols to disulfides, aromatic amines to azo-compounds, hydroquinone to p-benzoquinone, and benzylamine to benzaldehyde.
Used in Chemical Industry:
Barium manganate is useful for the selective oxidation of diols, making it a valuable reagent in the chemical industry for the synthesis of various organic compounds.

7787-35-1

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7787-35-1 Usage

References

N. Eastaugh, V. Walsh, T. Chaplin, R. Siddall, Pigment Compendium, 2008, ISBN: 978-0-7506-8980-9 https://en.wikipedia.org/wiki/Barium_manganate http://reag.paperplane.io/00000118.htm

Purification Methods

Wash the salt with conductivity H2O by decantation until the supernatant gives a faint test for Ba2+ . Remove excess H2O in a vacuum (IMPORTANT), then heat at 100o and the last traces of H2O are removed in a vacuum desiccator over P2O5. Store it over KOH. It disproportionates in hot H2O or dilute acid into Ba(MnO2)2 and MnO2, and is a mild oxidant. [Schlezinger & Siems J Am Chem Soc 46 1965 1924, Nyholm & Woolliams Inorg Synth XI 56 1968.]

Check Digit Verification of cas no

The CAS Registry Mumber 7787-35-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,7,8 and 7 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 7787-35:
(6*7)+(5*7)+(4*8)+(3*7)+(2*3)+(1*5)=141
141 % 10 = 1
So 7787-35-1 is a valid CAS Registry Number.
InChI:InChI=1/Ba.Mn.2H2O.2O.2H/h;;2*1H2;;;;/q;+2;;;;;;/p-2/rBaH2.H2MnO4/c;2-1(3,4)5/h1H2;2-3H

7787-35-1 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (L13172)  Barium manganate, tech. 90%   

  • 7787-35-1

  • 5g

  • 241.0CNY

  • Detail
  • Alfa Aesar

  • (L13172)  Barium manganate, tech. 90%   

  • 7787-35-1

  • 25g

  • 872.0CNY

  • Detail
  • Aldrich

  • (210196)  Bariummanganate  technical grade, 90%

  • 7787-35-1

  • 210196-5G

  • 468.00CNY

  • Detail
  • Aldrich

  • (210196)  Bariummanganate  technical grade, 90%

  • 7787-35-1

  • 210196-25G

  • 1,418.04CNY

  • Detail
  • Aldrich

  • (210196)  Bariummanganate  technical grade, 90%

  • 7787-35-1

  • 210196-100G

  • 4,286.88CNY

  • Detail

7787-35-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Barium manganate

1.2 Other means of identification

Product number -
Other names barium(2+),dioxido(dioxo)manganese

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7787-35-1 SDS

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