77870-69-0

Basic information

• Product Name: methyl 3,6-di-O-acetyl-2-benzamido-2,4-dideoxy-4-fluoro-α-D-glucopyranoside
• CAS NO: 77870-69-0
• Molecular Weight: 383.374
• Mol File: 77870-69-0.mol

Chemical Properties

• CAS DataBase Reference: methyl 3,6-di-O-acetyl-2-benzamido-2,4-dideoxy-4-fluoro-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3,6-di-O-acetyl-2-benzamido-2,4-dideoxy-4-fluoro-α-D-glucopyranoside(77870-69-0)
• EPA Substance Registry System: methyl 3,6-di-O-acetyl-2-benzamido-2,4-dideoxy-4-fluoro-α-D-glucopyranoside(77870-69-0)

Safety Data

• Hazardous Substances Data: 77870-69-0(Hazardous Substances Data)

Upstream product

• 77870-42-9 methyl 2-benzamido-3-O-benzyl-2-deoxy-4,6-di-O-mesyl-α-D-glucopyranoside 
• 77870-60-1 methyl 2-benzamido-3-O-benzyl-2-deoxy-α-D-galactopyranoside 
• 77870-41-8 methyl 2-benzamido-3-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 4288-73-7 methyl 2-benzamido-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 77870-66-7 methyl 2-benzamido-3-O-benzyl-2-deoxy-4-O-mesyl-6-O-trityl-α-D-galactopyranoside 
• 77870-67-8 N-((2S,3R,4R,5S,6R)-4-Benzyloxy-5-fluoro-2-methoxy-6-trityloxymethyl-tetrahydro-pyran-3-yl)-benzamide 
• 77870-40-7 methyl 2-benzamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 77870-68-9 methyl 2-benzamido-3-O-benzyl-2,4-dideoxy-4-fluoro-α-D-glucopyranoside 
• 108-24-7 acetic anhydride 
• 77870-71-4 methyl 2-benzamido-2,4-dideoxy-4-fluoro-α-D-glucopyranoside 

Downstream Products

• 77870-70-3 methyl 2-acetamido-3,6-di-O-acetyl-2,4-dideoxy-4-fluoro-α-D-glucopyranoside 

Relevant articles and documents

Synthesis of fluoro derivatives of 2-amino-2-deoxy-D-galactose and D-glucose

Selective fluoride displacement of the 6-mesyloxy group of methyl 2-benzamido-3-O-benzyl-2-deoxy-4,6-di-O-mesyl-α-D-glucopyranoside 4 gave the 6-fluoride 5.Subsequent removal of the blocking substituents afforded 2-amino-2,6-dideoxy-6-fluoro-D-glucose, is