77899-91-3Relevant academic research and scientific papers
INVESTIGATIONS IN THE SERIES OF DITHIOCARBAMIC ACID DERIVATIVES VII. REACTION OF METHYL N-(2-THIAZOLYL)DITHIOCARBAMATE WITH SOME NUCLEOPHILIC AGENTS
Bazavova, I. M.,Dubenko, R. G.,Pel'kis, P. S.
, p. 171 - 174 (2007/10/02)
The reaction of methyl N-(2-thiazolyl)dithiocarbamate with phenylhydrazine and hydrazine hydrate leads to the formation of 1-(2-thiazolyl)-4-phenylthiosemicarbazide and 4-(2-thiazolyl)thiosemicarbazide.With aromatic aldehydes the latter forms the 4-(2-thiazolyl)thiosemicarbazones of substituted benzaldehydes, and with phenyl isothiocyanate it forms 1-(2-thiazolyl)-6-phenylhydrazodithiocarbonamide.In the case of the reaction of methyl N-(2-thiazolyl)dithiocarbamate with cyanoacetamide the possibility of introducing a thiazolylthiocarbamoyl group into organic CH acids was demonstrated.
