77919-11-0

Basic information

• Product Name: N-(1-Phenylthiocarbonyl-1-methylaethyl)-2,2-diaethylmalonamid
• Synonyms: N-(1-Phenylthiocarbonyl-1-methylaethyl)-2,2-diaethylmalonamid
• CAS NO: 77919-11-0
• Molecular Weight: 336.455
• Mol File: 77919-11-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(1-Phenylthiocarbonyl-1-methylaethyl)-2,2-diaethylmalonamid(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-Phenylthiocarbonyl-1-methylaethyl)-2,2-diaethylmalonamid(77919-11-0)
• EPA Substance Registry System: N-(1-Phenylthiocarbonyl-1-methylaethyl)-2,2-diaethylmalonamid(77919-11-0)

Safety Data

• Hazardous Substances Data: 77919-11-0(Hazardous Substances Data)

Upstream product

• 4431-54-3 2,2-Diaethylmalonsaeuremonoamid 
• 108-98-5 thiophenol 
• 77918-99-1 N-(1-Dimethylcarbamoyl-1-methylaethyl)-2,2-diaethylmalonamid 

Relevant articles and documents

Synthese von 3,3-Dimethylperhydro-1,4-diazepin-2,5,7-trionen aus 3-Dimethylamino-2,2-dimethyl-2H-azirin und Malonsaeuremonoamiden

Synthesis of 3,3-Dimethylperhydro-1,4-diazepin-2,5,7-triones from 3-Dimethylamino-2,2-dimethyl-2H-azirine and Malonic Acid Monoamides.Reaction of aminoazirine 1 and malonic acid monoamides 5 in CH3CN yielded triamides of type 6 (Scheme 2), which were transformed to the corresponding phenylthioates 9 by treatment of a solution of 6 and thiophenol in CH3CN with HCl (Scheme 4).Cyclization of 9 to give the 1,4-diazepin-2,5,7-trione of type 10 was achieved with NaH in toluene at about 90 deg.It has been shown that 2-oxazolin-5-ones are intermediates in the selective cleavage of the therminal amide function of 6 (Scheme 3).