77944-39-9Relevant academic research and scientific papers
Arenesulfinamides as new reagents for the synthesis of allylic sulfoxides
Alajarín, Mateo,Pastor, Aurelia,Cabrera, José
, p. 995 - 998 (2007/10/03)
Reaction of arenesulfinamides with alkenes bearing allylic hydrogens in the presence of Yb(OTf)3/TMSC1 led to the corresponding allylic sulfoxides in good yields.
Synthesis of Allylic Sulfoxides from Alkenes by EtAlCl2-Catalyzed Ene Reaction with p-Toluenesulfinyl Chloride
Snider, Barry B.
, p. 3155 - 3156 (2007/10/02)
Ethylaluminum dichloride (EtAlCl2) catalyzes the ene reaction of alkenes with arylsulfinyl chlorides to give allylic sulfoxides since EtAlCl2 acts as a proton scavenger as well as a Lewis acid, reacting with the hydrogen chloride produced in the reaction to give aluminum trichloride and ethane.
