77944-42-4Relevant academic research and scientific papers
Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions
Maitro, Guillaume,Prestat, Guillaume,Madec, David,Poli, Giovanni
, p. 7449 - 7454 (2006)
Palladium-catalyzed allylic alkylation of sulfenate anions, generated from β-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.
Synthesis of Allylic Sulfoxides from Alkenes by EtAlCl2-Catalyzed Ene Reaction with p-Toluenesulfinyl Chloride
Snider, Barry B.
, p. 3155 - 3156 (2007/10/02)
Ethylaluminum dichloride (EtAlCl2) catalyzes the ene reaction of alkenes with arylsulfinyl chlorides to give allylic sulfoxides since EtAlCl2 acts as a proton scavenger as well as a Lewis acid, reacting with the hydrogen chloride produced in the reaction to give aluminum trichloride and ethane.
