77959-18-3Relevant academic research and scientific papers
CYCLOADDITION REACTIONS OF 1,3-DIPHENYLTHIAZOLOBENZIMIDAZOLE WITH FULVENE AND TROPONE SYSTEMS
Tsuge, Otohiko,Shirashi, Hidehiko,Noguchi, Michihiko
, p. 213 - 216 (2007/10/02)
1,3-Diphenylthiazolobenzimidazole (1) containing tetravalent sulfur reacts as a thiocarbonyl ylide dipole with 6,6-diphenylfulvene to give a mixture of two regioisomeric exo- adducts and endo-adduct.The reaction of 1 with tropone and 8,8-dicyanoheptafulvene proceeds via a cycloaddition to the C4-C5 and C1-C2 bond of the addend to afford the exo-adduct and desulfurized compound respectively.
