77965-70-9

Basic information

• Product Name: N-<(1E,3E)-4-methanoyl-1,3-butadienyl>benzenecarboxamide
• Synonyms: N-<(1E,3E)-4-methanoyl-1,3-butadienyl>benzenecarboxamide
• CAS NO: 77965-70-9
• Molecular Weight: 201.225
• Mol File: 77965-70-9.mol

Chemical Properties

• CAS DataBase Reference: N-<(1E,3E)-4-methanoyl-1,3-butadienyl>benzenecarboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-<(1E,3E)-4-methanoyl-1,3-butadienyl>benzenecarboxamide(77965-70-9)
• EPA Substance Registry System: N-<(1E,3E)-4-methanoyl-1,3-butadienyl>benzenecarboxamide(77965-70-9)

Safety Data

• Hazardous Substances Data: 77965-70-9(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 98-07-7 Benzotrichlorid 
• 617-89-0 furan-2-ylmethanamine 
• 3952-30-5 N-(2-furylmethyl)benzamide 
• 74-88-4 methyl iodide 

Relevant articles and documents

FORMATION AND REACTIVITY OF DILITHIATED N-FURFURYLBENZAMIDES. SYNTHESIS OF α-SUBSTITUTED N-FURFURYLBENZAMIDES

Dianion 3 can be efficiently and regioselectively generated from N-furfurylbenzamide with lithium diisopropylamide/tetrahydrofuran/-78 degC and react with various electrophiles to give α-substituted N-furfurylbenzamide derivatives in good yields.

Mechanism of the Fujiwara Reaction: Structural Investigation of Reaction Products from Benzotrichloride.

The mechanism of color development and the structures of chromophores of the Fujiwara reaction have been investigated by using benzotrichloride as a chromogenic reagent.Two products were isolated.NMR and mass spectroscopic investigation indicates that one of them is N2--N1-(1,3-butadienyl)benzamidine and that the other is N-benzenecarboxamide.In alkaline media, the former develops an intense red color; the latter becomes yellow.The formation of these chromophores is explained by the hydrolytic scission of pyridine rings in the benzal dipyridinium cation intermediate.