77987-32-7Relevant academic research and scientific papers
Total synthesis of (+)-diospongin A
Vaithegi, Kannan,Prasad, Kavirayani R.
, (2020)
Enantioselective total synthesis of 2,4,6-trisubstituted pyran natural product diospongin A is accomplished from benzaldehyde in 5 steps. Key reaction in the synthesis is the addition of a silyl enol ether derived from vinylogous aryl methyl ketone to chiral β-alkoxy aldehyde and subsequent oxa-Michael addition.
