78002-54-7

Upstream product

• 78002-56-9 hydroxymethyl-2 bicyclo <3.1.0>hexane-cis 
• 78002-45-6 ((1R,2R,5S)-6,6-Dichloro-bicyclo[3.1.0]hex-2-yl)-acetic acid methyl ester 
• 78002-45-6 (dichloro-6,6 bicyclo<3.1.0>hexyl-2)acetates de methyle 
• 78002-47-8 ((1R,2R,5S)-6,6-Dichloro-bicyclo[3.1.0]hex-2-yl)-acetic acid 
• 78002-47-8 acides(dichloro-6,6-bicyclo<3.1.0>hexyl-2)acetiques 
• 78002-52-5 (bicyclo<3.1.0>hexyl-2)acetate de methyle-trans 
• 20006-86-4 (cyclopentenyl-3)acetate de methyle 
• 78002-53-6 acide(bicyclo<3.1.0>hexyl-2)acetique, trans 
• 15733-76-3 (1R,2S,5S)-Bicyclo[3.1.0]hexane-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Ouverture de dichlorocyclopropanes en presence d'un nucleophile interne. Absence de participation intramoleculaire. Rearrangement concerte en chlorures allyliques

It is shown that a conveniently placed internal nucleophile (carboxyl group) is not involved with the rearrangement of a diclorocyclopropane into an allylic chloride.This result appears to support a concerted mechanism of a ?s2 + ?a2 type for this rearrangement.In the products obtained, the allylic chloride may undergo displacement either by solvent (H2O), leading to alcohols, or by the internal carboxyl group, leading to a lactone.