78009-99-1

Basic information

• Product Name: Phosphonium, [7-(2-hexyl-1,3-dioxolan-2-yl)heptyl]triphenyl-, bromide
• CAS NO: 78009-99-1
• Molecular Formula: C34H46O2P.Br
• Molecular Weight: 597.616
• Mol File: 78009-99-1.mol

Chemical Properties

• CAS DataBase Reference: Phosphonium, [7-(2-hexyl-1,3-dioxolan-2-yl)heptyl]triphenyl-, bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonium, [7-(2-hexyl-1,3-dioxolan-2-yl)heptyl]triphenyl-, bromide(78009-99-1)
• EPA Substance Registry System: Phosphonium, [7-(2-hexyl-1,3-dioxolan-2-yl)heptyl]triphenyl-, bromide(78009-99-1)

Safety Data

• Hazardous Substances Data: 78009-99-1(Hazardous Substances Data)

Upstream product

• 320343-47-3 2-{6-[(tetrahydropyran-2-yl)oxy]hexyl}-3-keto-1-nonanoic acid methyl ester 
• 320343-48-4 1-[(tetrahydropyran-2-yl)oxy]-8-tetradecanone 
• 163399-77-7 14-Bromo-tetradecan-7-one 
• 76190-93-7 14-hydroxytetradecan-7-one 
• 51756-07-1 3-oxononanoic acid methyl ester 
• 65785-44-6 6-iodohexanol, tetrahydropyranyl ether 
• 78009-93-5 2-(7-bromo-n-heptyl)-2-n-hexyl-1,3-dioxolane 
• 603-35-0 triphenylphosphine 

Downstream Products

• 157183-67-0 (2S,3S)-(E)-2-amino-3-hydroxy-2-hydroxymethyl-14-oxoicos-6-enoic acid 
• 78009-92-4 [(Z)-(1R,2S,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-12-(2-hexyl-[1,3]dioxolan-2-yl)-dodec-5-enyloxy]-tert-butyl-dimethyl-silane 
• 78009-92-4 [(E)-(1R,2S,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-12-(2-hexyl-[1,3]dioxolan-2-yl)-dodec-5-enyloxy]-tert-butyl-dimethyl-silane 
• 1421940-52-4 (5R,6S)-1-benzyl-6-[(3E)-10-(2-hexyl-1,3-dioxolan-2-yl)dec-3-en-1-yl]-8,8-dimethyl-3,7,9-trioxa-1-azaspiro[4.5]decan-2-one ? 
• 1421940-34-2 (5R,6S)-1-benzyl-6-[(3Z)-1-(2-hexyl-1,3-dioxolan-2-yl)dec-3-en-1-yl]-8,8-dimethyl-3,7,9-trioxa-1-azaspiro[4.5]decan-2-one ? 
• 78009-94-6 ((1R,2S,3R)-2,3-Bis-benzyloxy-1-benzyloxymethyl-4-{3-[6-(2-hexyl-[1,3]dioxolan-2-yl)-hexyl]-oxiranyl}-butoxy)-tert-butyl-dimethyl-silane 
• 78009-97-9 (E)-(3R,4R)-2-Amino-3,4-bis-benzyloxy-2-benzyloxymethyl-13-(2-hexyl-[1,3]dioxolan-2-yl)-tridec-6-enenitrile 
• 78009-96-8 (E)-(3S,4R)-1,3,4-Tris-benzyloxy-13-(2-hexyl-[1,3]dioxolan-2-yl)-tridec-6-en-2-one 
• 78009-95-7 (E)-(2R,3R,4R)-1,3,4-Tris-benzyloxy-13-(2-hexyl-[1,3]dioxolan-2-yl)-tridec-6-en-2-ol 
• 145401-48-5 sphingofungin F 
• 199658-16-7 (4R,5S)-4-[(E)-(R)-1-Benzyloxy-10-(2-hexyl-[1,3]dioxolan-2-yl)-dec-3-enyl]-2,2-dimethyl-5-(2,2,2-trichloro-acetylamino)-[1,3]dioxane-5-carboxylic acid methyl ester 
• 176703-37-0 methyl (4S,5S)-4-acetoxymethyl-5-[(3E)-11,11-ethylenedioxyheptadec-3-enyl]-2-phenyl-Δ²-oxazoline-4-carboxylate 

Relevant articles and documents

An efficient and convenient approach to the total synthesis of sphingofungin

As a new member of the sphingofungin family, sphingofungin F exhibits interesting physiological activities with a structural unit of an α-substituted alanine. Described herein is an efficient and convenient stereoselective synthesis of sphingofungin F from L-(+)-tartaric acid, which utilizes Sharpless asymmetric epoxidation of allylic alcohol and Lewis acid-catalyzed intramolecular epoxideopening reaction with an N-nucleophile, to introduce the other two desired stereogenic centers. Side chain functionality was incorporated into the chiral segment using a Wittig reaction.

Asymmetric Total Synthesis of ISP-I (Myriocin, Thermozymocidin), a Potent Immunosuppressive Principle in the Isaria sinclairii Metabolite

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