78013-78-2Relevant articles and documents
Syntheses and Reactions of 3-C-Methyl-branched Glycals of the D-Series. Preparations of the Isomers of Terminal Disaccharides in Olivomycin A and Mithramycin
Thiem, Joachim,Elvers, Juergen
, p. 1442 - 1454 (2007/10/02)
Syntheses of D-olivomycal (6) and D-mycaral (9) are achieved starting with D-rhamnal (4) or D-digitoxal (5), respectively.The transformation of 9 to methyl α-D-mycaroside (12) represents a configurational assignment at the branching point.With methyllithi