78019-35-9Relevant academic research and scientific papers
Hydroxy Sulfoxides Derived from Norbornene: Determination of Stereochemistry, and Synthesis by Stereoselective Oxidation
Beckwith, Athelstan L. J.,Rodgers, John R.,Wagner, Rudolf D.
, p. 989 - 996 (2007/10/02)
The structure (5) of one of the hydroxy sulfoxides formed by thiol-oxygen cooxidation of norbornene has been determined by X-ray diffraction.Other products have been related to it by appropriate chemical transformations.The stereospecific, or highly stere
Thiol-Oxygen Cooxidation Reactions of Cyclopentene, cis- and trans-But-2-ene, Norbornene, and Norbornadiene
Beckwith, Athelstan L. J.,Wagner, Rudolf D.
, p. 3638 - 3645 (2007/10/02)
Thiol-oxygen cooxidation (TOCO) of olefins, followed by reduction of the initially formed hydroperoxides with triphenylphosphine, affords β-hydroxy sulfides in moderate to good yields.The structures of the major products from cis- and trans-but-2-ene and
