78052-24-1Relevant academic research and scientific papers
Reactions of Ketone Hydrazones and β-Keto Enamines with Disulfur Dichloride. New Synthesis of Thioketones and 5H-1,2,3-Dithiazoles
Okazaki, Renji,Inoue, Kaoru,Inamoto, Naoki
, p. 3541 - 3545 (1981)
Ketone hydrazones react with disulfur dichloride in the presence of triethylamine to afford thioketones in good yields.The reaction mechanism involving N-thiosulfinylamine (R2C=N-N=S=S) and S-thioxothioketone (R2C=S=S) is proposed.The formation of di-t-bu
