78060-08-9Relevant academic research and scientific papers
Novel heterocyclic aminophosphonic acids derived from furan and thiophene
Boduszek,Vegh,Korenova,Uher
, p. 1271 - 1275 (2007/10/03)
Heterocyclic derivatives of aminomethylphosphonic acid were obtained in a one-pot procedure, by treatment of the corresponding heterocyclic aldimines with a mixture of trimethyl phosphite and bromotrimethylsilane (BrTMS). A reagent for phosphorylation of
Application of bromotrimethylsilane and trialkyl phosphites for convenient and effective synthesis of aminophosphonic acids and corresponding monoalkyl and dialkyl esters
Boduszek
, p. 663 - 672 (2007/10/03)
Application of bromotrimethylsilane (Br-TMS) in a mixture with trialkyl phosphite for synthesis of various aminophosphonic acids and esters was investigated. It was found, that appropriate mixtures of Br-TMS and trimethyl phosphite or triethyl phosphite were effective reagents for phosphorylation of various aldimines, obtained from aromatic and heteroaromatic aldehydes. Products of these reactions were corresponding aminophosphonic acids, or corresponding dialkyl or monoalkyl esters, respectively.
