780820-91-9Relevant academic research and scientific papers
Synthetic ventures inspired by biosynthetic hypotheses: the evolution of a method for the oxidative amidation of phenols
Ciufolini, Marco A.,Canesi, Sylvain,Ousmer, Malika,Braun, Norbert A.
, p. 5318 - 5337 (2007/10/03)
We describe the development of a technique for the oxidative conversion of 4-alkyl phenols to derivatives of the corresponding 4-alkyl-4-amino-2,5-cyclohexanediones. This transformation, which was inspired by biogenetic considerations, constitutes a key s
Fully stereocontrolled total syntheses of (-)-cylindricine C and (-)-2-epicylindricine C: A departure in sulfonamide chemistry
Canesi, Sylvain,Bouchu, Denis,Ciufolini, Marco A.
, p. 4336 - 4338 (2007/10/03)
A common intermediate was used in the total syntheses of (-)-cylindricine C and (-)-2-epicylindricine C (see picture) in a process that involves the initial oxidative spirocyclization of a phenolic sulfonamide. The remainder of the molecules is constructe
