78088-98-9

Upstream product

• 59524-02-6 N-tert-butoxycarbonyl-L-serine benzyl ester 
• 23680-31-1 BOC-O-benzyl-L-serine 
• 1262890-83-4 (S)-benzyl 3-((S)-3-(benzyloxy)-2-(tert-butoxycarbonylamino)propanoyloxy)-2-(tert-butoxycarbonylamino)propanoate 
• 78088-97-8 (S)-3-Benzyloxy-2-tert-butoxycarbonylamino-propionic acid (S)-2-tert-butoxycarbonylamino-2-(9,10-dioxo-9,10-dihydro-anthracen-2-ylmethoxycarbonyl)-ethyl ester 

Downstream Products

• 1262890-84-5 (S)-benzyl 3-((S)-3-((S)-3-(benzyloxy)-2-(tert-butoxycarbonylamino)propanoyloxy)-2-(tert-butoxycarbonylamino)propanoyloxy)-2-(2,3-bis(benzyloxy)benzamido)propanoate 
• 78089-00-6 2-tert-Butoxycarbonylamino-acrylic acid (S)-2-tert-butoxycarbonylamino-2-(9,10-dioxo-9,10-dihydro-anthracen-2-ylmethoxycarbonyl)-ethyl ester 
• 78088-97-8 (S)-3-Benzyloxy-2-tert-butoxycarbonylamino-propionic acid (S)-2-tert-butoxycarbonylamino-2-(9,10-dioxo-9,10-dihydro-anthracen-2-ylmethoxycarbonyl)-ethyl ester 
• 78089-01-7 (S)-3-Benzyloxy-2-tert-butoxycarbonylamino-propionic acid (S)-2-tert-butoxycarbonylamino-2-[(S)-2-tert-butoxycarbonylamino-2-(9,10-dioxo-9,10-dihydro-anthracen-2-ylmethoxycarbonyl)-ethoxycarbonyl]-ethyl ester 

Relevant academic research and scientific papers

Facile synthesis of salmochelin S1, S2, MGE, DGE, and TGE

Salmochelin S1, S2, MGE, DGE, and TGE were prepared through amide bond connection of an aryl C-glucosyl acyl chloride (Ar1COCl) and serine ester amines, followed by hydrogenolysis of the per-benzylated precursors. Each synthesis employed a highly diastereoselective Ni-catalyzed Negishi approach to the aryl C-glycoside subunit.