78120-97-5Relevant academic research and scientific papers
Oxidative Generation of Thioalkyl Cations from 2-Tributylstannyl-1,3-dithianes and 1-(Tributylstannyl)alkyl Sulfides and Their Reactions with Olefinic Nucleophiles
Narasaka, Koichi,Arai, Noriyoshi,Okauchi, Tatsuo
, p. 2995 - 3003 (2007/10/02)
2-Tributylstannyl-1,3-dithianes and 1-(tributylstannyl)alkyl sulfides are oxidized with ammonium hexanitratocerate(IV) or ferrocenium hexafluorophosphate to generate their cation radicals, which dissociate into the carbocations and tributylstannyl radical
SYNTHESIS OF 2-ACYLMETHYL- AND 2-ACYLMETHYLENEBENZO-1,3-DITHIOLES FROM α-ALKYNYL KETONES
Elokhina, V. N.,Nakhmanovich, A. S.,Karnaukhova, R. V.,Kalikhman, I. D.,Voronkov, M. G.
, p. 235 - 239 (2007/10/02)
The reaction of α-alkynyl ketones with o-phenylenedithiol, which leads to the formation of 2-acylmethylbenzo-1,3-dithioles, was investigated.Reactions of the latter with hydrazine hydrate and hydroxylamine and oxidation were realized.Difficult-to-obtain 2
