78133-67-2

Basic information

• Product Name: N-phenyl-1-trimethylsilylmethylbicyclo<2.2.1>hept-5-ene-2,3-endo-dicarboximide
• CAS NO: 78133-67-2
• Molecular Weight: 325.483
• Mol File: 78133-67-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-phenyl-1-trimethylsilylmethylbicyclo<2.2.1>hept-5-ene-2,3-endo-dicarboximide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-1-trimethylsilylmethylbicyclo<2.2.1>hept-5-ene-2,3-endo-dicarboximide(78133-67-2)
• EPA Substance Registry System: N-phenyl-1-trimethylsilylmethylbicyclo<2.2.1>hept-5-ene-2,3-endo-dicarboximide(78133-67-2)

Safety Data

• Hazardous Substances Data: 78133-67-2(Hazardous Substances Data)

Upstream product

• 941-69-5 N-phenyl-maleimide 
• 4206-67-1 iodo(trimethylsilyl)methane 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 78133-71-8 7-syn-hydroxy-5-exo-methylene-N-phenylbicyclo<3.2.1>heptane-2,3-dicarboximide 

Relevant articles and documents

The Reaction between Bis(trimethylsilyl)cyclopentadiene and Dichloroketen, and the Diels-Alder Reactions between N-Phenylmaleimide and Two Silylated Methylcyclopentadienes

Bis(trimethylsilyl)cyclopentadiene reacts with dichloroketen to give only the adduct (7) derived from the 2,5-disilylated isomer (5).Methyl(trimethylsilyl)cyclopentadiene (18) and trimethylsilylmethylcyclopentadiene (21) give Diels-Alder adducts (19) and (20) and (22) and (23) in which the regioselectivity is unaffected by the presence of the silyl group.Epoxidation of the edduct (22) and acid-catalysed opening of the epoxide lead to formation of the exo-methylenenorbornane (26) in a rearrangement controlled by the presence of the silyl group.