78153-85-2Relevant academic research and scientific papers
Stereoselective α-Glucosylation with Tetra-O-benzyl-α-D-glucose and a Mixture of Trimethylsilyl Bromide, Cobalt(II) Bromide, Tetrabutylammonium Bromide, and a Molecular Sieve. A Synthesis of 3,6-Di-O-(α-D-glucopyranosyl)-D-glucose
Koto, Shinkiti,Morishima, Naohiko,Kusuhara, Chiharu,Sekido, Shigeko,Yoshida, Toyosaku,Zen, Shonosuke
, p. 2995 - 2999 (2007/10/02)
A mixture of trimethylsilyl bromide, cobalt(II) bromide, tetrabutylammonium bromide, and a molecular sieve (4A) is effective for the stereoselective, one-stage α-glucosylation of alcohol with 2,3,4,6-tetra-O-benzyl-α-D-glucopyranose in dichloromethane.Using this procedure, several disaccharide derivatives as well as O-α-D-glucopyranosyl-(1 -> 3)-O- 6)>-D-glucopyranose are synthesized.
ONE-STAGE α-GLUCOSYLATION USING TETRA-O-BENZYL-α-D-GLUCOSE AND MIXTURE OF TRIMETHYLSILYL BROMIDE, COBALT(II) BROMIDE, TETRABUTYLAMMONIUM BROMIDE, AND MOLECULAR SIEVE
Morishima, Naohiko,Koto, Shinkiti,Kusuhara, Chiharu,Zen, Shonosuke
, p. 427 - 428 (2007/10/02)
The one-stage α-glucosylation using 2,3,4,6-tetra-O-benzyl-α-D-glucopyranose and a mixture of trimethylsilyl bromide, cobalt(II) bromide, and tetrabutylammonium bromide in the presence of molecular sieve is presented.
