78176-45-1Relevant academic research and scientific papers
NOVEL UNCATALYSED MICHAEL REACTIONS OF LITHIUM TRIALKYLALKYNYLBORATES WITH ALKYLIDENEMALONATES AND ALKYLIDENEACETOACETATES.
Pelter, Andrew,Rao, J. Madhusudhana
, p. 797 - 800 (1981)
Alkynylborates and alkylidenemalonates and alkylideneacetoacetates undergo unusual Michael reactions which involve migration of alkyl groups from boron to carbon, to yield products of synthetic value.
The Chemistry of Organoborates. Part 8. Unique Michael Reactions of Lithium Trialkylalkynylborates
Pelter, Andrew,Hughes, Lynn,Rao, J. Madhusudhana
, p. 719 - 722 (2007/10/02)
Lithium trialkylalkynylborates undergo unique Michael reactions involving migration of an alkyl group from boron to carbon.Oxidation or hydrolysis of the vivylboranes so produced yields compounds of synthetic potential.The generality and limitations of the Michael reactions are discussed.
