78179-65-4Relevant academic research and scientific papers
14β-Hydroxysteroids, II. - The Prins Reaction of Lumihecogenin Acetate
Welzel, Peter,Janssen, Bernd,Duddeck, Helmut
, p. 546 - 564 (2007/10/02)
Photochemical rearrangement of hecogenin acetate (1) into the unsaturated aldehyde 5 followed by a Prins reaction leads efficiently to the 14β-hydroxysteroids 7a and 10a.The configuration of 7a, 10a, and 9a at C-13 and C-14 has been determined by chemical correlation and spectroscopically (1H-NMR, 13C-NMR, CD).
