78191-64-7Relevant articles and documents
HYDROBORATION D'AMINES ALLYLIQUES. REACTIVITE DES ORGANOBORANES
Baboulene, Michel,Torregrosa, Jean-Luc,Speziale, Vincent,Lattes, Armand
, p. 565 - 570 (2007/10/02)
Hydroboration of differently substituted allylic amines has been studied systematically.It was possible to demonstrate the importance of the hydroboration agent on the formation of aminoboranes.Oxidation of aminoboranes by hydrogen peroxyde in basic medium has ben examined and has led, with good yields, to primary aminoalcohols or a mixture of isomeric aminoalcohols.The influence of steric hindrance on the double bond and that of substitution of the nitrogen atom have been shown.