782-76-3

Usage

InChI:InChI=1/C14H13NO/c1-11-6-8-13(9-7-11)15-10-12-4-2-3-5-14(12)16/h2-10,15H,1H3

Upstream product

• 106-49-0 p-toluidine 
• 90-02-8 salicylaldehyde 
• 89-95-2 2-methyl-benzyl alcohol 
• 54-21-7 sodium salicylate 
• 53565-66-5 6-[1-p-Tolylamino-meth-(Z)-ylidene]-cyclohexa-2,4-dienone 
• 53565-66-5 6-[1-p-Tolylamino-meth-(Z)-ylidene]-cyclohexa-2,4-dienone 

Downstream Products

• 1847-00-3 N-(4-methylphenyl)-2-oxochromene-3-carboxamide 
• 107266-70-6 2-[(E)-2-(2-Hydroxy-phenyl)-vinyl]-3-p-tolyl-3H-benzo[h]quinazolin-4-one 
• 89-95-2 2-methyl-benzyl alcohol 
• 97095-05-1 6a,7,10,10a-Tetrahydro-8,9-dimethyl-N-(4-methylphenyl)-6-oxo-6H-5-oxaphenanthren-6a-carboxamid 
• 97095-09-5 6a,7,8,9,10,11,12,12a-Octahydro-N-(4-methylphenyl)-6-oxo-6H-5-oxabenzanthracen-6a-carboxamid 
• 130191-24-1 N-(2-methoxybenzyl)-4-methylaniline 
• 16884-30-3 [VO(OC₆H₄CHNC₆H₄CH₃)2] 
• 28548-12-1 {PbCl₂(C₁₄H₁₂NO)2} 
• 53295-02-6 tris(salicylidene-p-toluidinato)-cobalt(III) 
• 29933-35-5 salicylidene-p-toluidine Cu(II)-complex 

Relevant academic research and scientific papers

Synthesis, structural characterization, and catalytic activity of ruthenium(II) monocarbonyl complexes with bidentate Schiff base and triphenylphosphine ligands

Treatment of [RuHCl(CO)(PPh3)3] with equal amounts of equiv bidentate Schiff base 2[(4-chloro-phenylimino)-methyl]-phenol (HL-Cl) or 2(p-tolylimino-methyl)-phenol (HL-Me) or 2[(4-nitro-phenylimino)-methyl]-phenol (HL-NO2) in the presence of triethylamine afforded [RuCl(2-N,O-L-Cl) (CO)(PPh3)2] (1), [RuCl(2-N,O-L-Me)(CO)(PPh3)2] (2), and [RuCl( 2-N,O-L-NO2)(CO)(PPh3)2] (3), respectively The molecular structures of 1, 2, and 3·1.5C6H14 have been determined by single-crystal X-ray crystallography Complexes 1-3 were used for oxidation of primary and secondary alcohols to aldehydes and ketones as catalysts in the presence of N-methylmorpholine-N-oxide 2013

Facile synthesis, solublization studies and anti-inflammatory activity of amorphous zinc(Ii) centered aldimine complexes

In this study, Zn(II) centered complexes with aldimine derivatives were synthesized using green solvent, polyethylene glycol (PEG-400) and amorphous complexes were characterized by FT-IR, multinuclear (1H and13C NMR), elemental and thermal analysis. Thermogravimetric analysis indicated the extended thermal stability of the synthesized complexes. All the Zn(II) complexes show very significant photoexcitation in the range of 318 – 384 nm and photoemission in the range of 502 – 562 nm. Among all the complexes, Zn(II) complex (3Zn) showed minimum band gap value, 2.35 eV. These amorphous complexes have been reported for their wide applications in biomedical sciences. The synthesized aldimine ligands and Zn(II) complexes were investigated for anti-inflammatory activity and these complexes showed more anti-inflammatory potential than the corresponding aldimine ligands. The solubilization of zinc complexes in sodium dodecyl sulphate was also investigated to reveal the interaction of metal complexes by using UV-Visible spectroscopy and electrical conductivity measurements.

Synthesis, characterization and anti-cancer studies of Mn(II), Cu(II), Zn(II) and Pt(II) dithiocarbamate complexes - crystal structures of the Cu(II) and Pt(II) complexes

Mn(II), Cu(II), Zn(II) and Pt(II) complexes of 2-((p-tolylamino)methyl)phenolyldithiocarbamate were synthesized and characterized by elemental analyses and spectroscopic techniques. Spectroscopic studies indicate four coordinate geometry around the metal(

Influence of substituents on the structure of Schiff bases Cu(II) complexes

The relationship between molecular conformation and substituent effects of salicylaldehyde Schiff-base Cu(II) complexes was explored. For this study, eight samples of the complexes Cu(Sal-X)2 (X = OMe, Me, H, F, Cl, Br, CF3 and CN) w

Synthesis of novel Schiff bases using green chemistry techniques; antimicrobial, antioxidant, antiurease activity screening and molecular docking studies

Schiff base derivatives were synthesized in this study via conventional, microwave irradiation and ultrasound sonication methods. Optimization conditions were examined for several parameter such as solvent, reaction time and yield. After determining the o

Effect of substituents on the UV spectra of supermolecular system: Silver nanoparticles with bi-aryl Schiff bases containing hydroxyl

Effect of substituents on the ultraviolet (UV) spectra of supermolecular system involving silver nanoparticles (AgNPs) and Schiff bases was investigated. AgNPs and 49 samples of model compounds (MC), bi-aryl Schiff bases containing hydroxyl (XBAY, involving 4-OHArCH?NArY, 2-OHArCH?NArY, XArCH?NAr-4′-OH, and XArCH?NAr-2′-OH), were synthesized. The size of AgNPs was characterized by transmission electron microscopy (TEM), and the UV absorption spectra of AgNPs, XBAYs, and MC-AgNPs mixed solutions were measured, respectively. The results show that (1) the size of AgNPs is larger in MC-AgNPs solutions than that in AgNPs solution due to the distribution of MC molecules on the surface of AgNPs; (2) the UV absorption wavelength of XBAYs changes in the action of AgNPs and their wavelength shift exists limitation between XBAY and MC-AgNPs solutions; and (3) the wavelength shift limit of MC-AgNPs (λWSL) is influenced by the substituents X and Y and the position of hydroxyl OH. The wavenumber ΔνWSL of λWSL can be quantified by employing the excited-state substituent constant σexCC and Hammett constant σ of substituents X and Y. Comparing with the 4-OH, the 4′-OH makes the ΔνWSL a red shift, whereas the 2′-OH, comparing with the 2-OH, makes the ΔνWSL a blue shift.

AIPE-active platinum(ii) complexes with tunable photophysical properties and their application in constructing thermosensitive probes used for intracellular temperature imaging

Aggregation-induced phosphorescent emission (AIPE) luminogens based on phosphorescent transition metal complexes have many application advantages in bioimaging compared with fluorescent organic dyes because of their long excitation lifetime and reduced ph

Copper-Catalyzed Asymmetric Annulation Reactions of Carbenes with 2-Iminyl- or 2-Acyl-Substituted Phenols: Convenient Access to Enantioenriched 2,3-Dihydrobenzofurans

We have developed a method for the highly diastereo- and enantioselective construction of 2,3-dihydrobenzofurans bearing tetrasubstituted carbon stereocenters by means of annulation reactions between carbenes and 2-iminyl- or 2-acyl-substituted phenols through catalysis by readily accessible copper(I)/bisoxazoline catalysts under mild conditions. These reactions feature a unique mechanism in which the copper catalyst serves a dual function: first it reacts with the diazo compound to generate a metal carbene, and second, upon formation of an oxonium ylide, it acts as a Lewis acid to activate the imine or ketone for diastereo- and enantioselective cyclization.

Synthesis, spectroscopic characterization, DFT calculations, and antimicrobial activities of N-arylsalicylaldiminate derivatives of diorganotin(IV)

Equimolar reaction of di-n-butyltin(IV) complexes of bidentate Schiff bases of the type [(n-Bu)2Sn(sb)Cl] with sodium salt of mono-functional bidentate ligands in THF-benzene solution afforded structurally interesting complexes of the type [(n-

Synthesis, spectral studies and DFT calculation of copper(II) complexes with mixed ligands

The reaction of copper(II) chloride with Schiff bases and alkanolamines in 1:1:1 molar ratio(s) resulted a series of mixed ligand copper(II) complexes of general formula [Cu(sb)(aa)] (1-6), [where sb = Schiff base; salicylidine-1-aminobenzene (sabH) (1,4)