78220-18-5Relevant articles and documents
Thermolysis of 2,2-Dihydro-1,4,2-oxazaphosphol-4-enes, II. A Simple Synthesis for Fluorine Substituted N-Vinylimidoyl Chlorides
Burger, Klaus,Goth, Herbert,Burgis, Eduard
, p. 353 - 358 (2007/10/02)
3,3-Bis(chlorodifluoromethyl)-2,2,2-trimethoxy-2,2-dihydro-1,4,2-oxazaphosphol-4-enes (2) at room temperature, 3,3-bis(chlorodifluoromethyl)-2,2,2-triphenoxy-2,2-dihydro-1,4,2-oxazaphosphol-4-enes (3) at 140-145 deg C undergo cycloelimination of trimethyl and triphenyl phosphate, respectively, with formation of N--imidoyl chlorides (4) in high yields. - Keywords: Phosphorus Compounds, Cycloreversion Reactions, Chlorine Shift, 2-Azabuta-1,3-dienes