78255-60-4Relevant academic research and scientific papers
2,4-Bis(o-tolyl)-3-azabicyclo[3.3.1]nonan-9-one
Vijayalakshmi,Parthasarathi,Venkatraj,Jeyaraman
, p. 1240 - 1241 (2000)
The crystal structure of 2,4-bis(o-tolyl)-3-azabicyclo[3.3.1]-nonan-9-one shows that the bicyclic ring system adopts the chair-chair conformation. The phenyl rings are equatorially disposed with respect to the bicyclic ring. A slight deviation is seen from the chair conformation in the case of cyclohexane ring. A mixture of cyclohexanone, o-tolualdehyde and ethanol was added to a warm solution of ammonium acetate in absolute ethanol. Crystals of the ketone were separated out and were washed.
Spontaneous generation of chirality and chiroptical spectra of N-nitroso-2,4-diaryl-3-azabicyclo[3.3.1]nonanes
Olszewska, Teresa,Milewska, Maria J.,Gdaniec, Maria,Polonski, Tadeusz
experimental part, p. 278 - 283 (2012/06/15)
The crystal structures of several bicyclic N-nitrosamines indicate that they crystallize in the chiral (Sohncke) space group P212 121 as conglomerates. This allows the resolution of these compounds by manual picking of the
