78303-49-8Relevant academic research and scientific papers
Manganese(III) acetate promoted acetoxylation of various α,β-unsaturated cyclopentanones
Tanyeli, Cihangir,Tosun, Ay?egül,Turkut, Engin,Sezen, Bengü
, p. 1055 - 1058 (2007/10/03)
We describe the results of manganese(III) acetate based regioselective oxidation of various α,β-unsaturated cyclopentanones leading to α′-acetoxy α,β-unsaturated cyclopentanones in good yields. Products due to monophenyl and diphenyl substituted dimerizat
REACTION OF ALLYLSILANE WITH α-NITRO OLEFIN AND ITS DEVELOPMENT TO SYNTHESIS OF CYCLOPENTENONE
Ochiai, Masahito,,Arimoto, Masao,Fujita, Eiichi
, p. 1115 - 1118 (2007/10/02)
Michael addition of allylsilane to α-nitro olefin in the presence of AlCl3 proceeded smoothly at low temperature to give unsaturated nitronic acid, which was converted into the γδ-enone using aqueous Ti (III).Transformation of the enone into the 1,4-diketone followed by the intramolecular aldol condensation with the latter provided a convenient new synthesis of cyclopentanone.
