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SYNTHESES AND CHARACTERIZATION OF CYCLOPALLADATED COMPLEXES OF 2-PHENYLTHIAZOLE
Hiraki, Katsuma,Fuchita, Yoshio,Takakura, Shinji
, p. 273 - 280 (1981)
2-Phenylthiazole reacts with palladium(II) acetate to give a new cyclopalladated, acetato-bridged binuclear complex, 2> .A chloro-bridged analogue, 2>, produced by the reaction of the acetato-bridged complex with sodium chloride, undergoes bridge-splitting reactions with triphenylphosphine, 3,5-lutidine, and thallium(I) acetylacetonate to give the corresponding mononuclear cyclopalladated complexes.All the new complexes were characterized by means of elemental analysis, and IR and NMR spectroscopy.Reactions of 2> with methyl vinyl ketone and styrene afford 2-phenylthiazole and 2-(2'-thiazolyl)stilbene, respectively.
