783322-55-4Relevant academic research and scientific papers
Regio- and stereoselective transfer of p-toluenesulfonamido group from sulfur to carbon: Preparation of aminoalcohol derivatives from allylalcohols
Raghavan, Sadagopan,Naveen Kumar, Ch.,Tony,Ramakrishna Reddy,Ravi Kumar
, p. 7231 - 7234 (2004)
Stereospecific transformation of sulfilimines to sulfoxides and regio- and stereoselective transformation of alkenes to bromosulfonamides is disclosed. A novel methodology for the regio- and stereoselective synthesis of amino alcohol derivatives from allylalcohols/ethers via intramolecular nucleophilic participation by the sulfilimine moiety is disclosed. The sulfilimine moiety is stereospecifically transformed to a sulfinyl moiety with an inverted configuration. The reaction is general and affords highly functionalised products.
