78335-79-2Relevant academic research and scientific papers
Rhodium-catalysed linear-selective alkyne hydroacylation
Poingdestre, Sarah-Jane,Goodacre, Jonathan D.,Weller, Andrew S.,Willis, Michael C.
supporting information; experimental part, p. 6354 - 6356 (2012/07/14)
The use of the electron-rich diphosphine ligand, dcpe, allows the efficient and highly linear selective hydroacylative coupling of aldehydes, including aryl examples, with a range of alkynes.
Rhodium-catalyzed branched-selective alkyne hydroacylation: A ligand-controlled regioselectivity switch
Gonzalez-Rodriguez, Carlos,Pawley, Rebekah J.,Chaplin, Adrian B.,Thompson, Amber L.,Weller, Andrew S.,Willis, Michael C.
supporting information; experimental part, p. 5134 - 5138 (2011/06/26)
It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dpp
Sulfur analogues of psychotomimetic agents. Monothio analogues of mescaline and isomescaline
Jacob III,Shulgin
, p. 1348 - 1353 (2007/10/02)
2 monothio analogues of mescaline and 3 monothio analogues of 2,3,4-trimethoxyphenethylamine (isomescaline) have been synthesized and characterized. Only the 2 mescaline analogues (3- and 4-thiomescaline) were found to be psychotomimetics in man, being 6
