783356-71-8

Basic information

• Product Name: methyl 4-((2-((tert-butoxycarbonyl)amino)ethyl)thio)benzoate
• Synonyms: methyl 4-((2-((tert-butoxycarbonyl)amino)ethyl)thio)benzoate
• CAS NO: 783356-71-8
• Molecular Weight: 311.402
• Mol File: 783356-71-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4-((2-((tert-butoxycarbonyl)amino)ethyl)thio)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-((2-((tert-butoxycarbonyl)amino)ethyl)thio)benzoate(783356-71-8)
• EPA Substance Registry System: methyl 4-((2-((tert-butoxycarbonyl)amino)ethyl)thio)benzoate(783356-71-8)

Safety Data

• Hazardous Substances Data: 783356-71-8(Hazardous Substances Data)

Upstream product

• 619-44-3 methyl 4-iodobenzoate 
• 67385-10-8 di-tert-butyl(disulfanediylbis(ethane-2,1-diyl))dicarbamate 
• 6302-65-4 methyl 4-mercaptobenzoate 

Downstream Products

• 1366131-53-4 methyl 4-(2-aminoethylsulfanyl)benzoate hydrochloride 
• 783356-74-1 methyl 4-(2-tert-butoxycarbonylaminoethylsulfonyl)benzoate 

Relevant articles and documents

A visible-light photocatalytic thiolation of aryl, heteroaryl and vinyl iodides

The general catalytic synthesis of aryl and vinyl thioethers from readily available halides remains a challenge. Herein we report a unified method for the thiolation of aryl and vinyl iodides with dialkyl disulfides using visible light photoredox catalysis. A range of thioether products bearing diverse functional groups can be accessed in high yield and with excellent chemoselectivity. We demonstrate the versatility of this method through the expedient synthesis of a family of thioether-rich natural products. A detailed investigation of the photocatalytic mechanism is presented from both steady-state and time-resolved luminescent quenching as well as transient absorption spectroscopy experiments.