78336-52-4Relevant academic research and scientific papers
Reactions of Complex Ligands, XXI. Competing Olefin Scission and Cyclopropanation of Enamines in the Reaction with Carbene Complexes
Doetz, Karl Heinz,Pruskil, Ingrid
, p. 1980 - 1982 (2007/10/02)
Pentacarbonyl(methoxyphenylcarbene)chromium (1) reacts with 1-phenyl-1-piperidinoethene (2) to give both 1-methoxy-1,2-diphenyl-2-piperidinocyclopropane (3) and pentacarbonyl(phenylpiperidinocarbene)chromium (4).The reaction of 1 with 1-pyrrolidino-1-cyclopentene (5) leads to insertion of the alkene into the metal carbene bond with formation of 6.
