78342-31-1Relevant academic research and scientific papers
Highly Stereoselective Routes to Functionalized Geminal Alkyl Derivatives of Carbohydrates
Fraser-Reid, Bert,Tsang, Raymond,Tulshian, Deen Bundhu,Sun, King Mo
, p. 3764 - 3767 (2007/10/02)
2-, 3-, and 4-Keto derivatives of some α-D-hexopyranosides react with Ph3P=CHCOOEt to give a single geometric isomer in each case, which is readily converted into an allyl vinyl ether.Claisen rearrangements of the latter proceed with high stereoselectivit
